Optimization of a Multi-step Model for the Auto-ignition of Dimethyl Ether in a Rapid Compression Machine

نویسندگان

  • Elisa Toulson
  • Casey M. Allen
  • Dennis J. Miller
  • Harold J. Schock
  • Tonghun Lee
چکیده

The research presented here describes the numerical optimization of a multi-step ignition model to predict the auto-ignition of dimethyl ether (DME) in a rapid compression machine. The multi-step modeling concept is aimed at capturing the ignition behavior of new oxygenated fuel blends, where detailed or reducedmechanisms are not available. Experimental data for the ignition ofDME/O2/N2mixtures atmore than 60 different conditions were used by the optimizer to determine the 26 kinetic parameters of themultistep model that are unique to each individual fuel or fuel blend. The optimization was performed for conditions with compressed pressures in the range of 10-20 bar, compressed temperatures from 615 to 735 K, and equivalence ratios of 0.43, 0.75, and 1.5. In this region, DME exhibits two-stage ignition behavior. The first and overall ignition delay characteristics predicted by the multi-step model with the DME-optimized constants show good agreement with the experimental data for the majority of conditions tested.

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تاریخ انتشار 2010